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Archibald E. Garrod 
Full text facsimile of his book, Inborn Errors of Metabolism, published in 1923.
http://www.esp.org/books/garrod/inborn-errors/facsimile/
Sir Archibald Garrod 
The one gene - one enzyme hypothesis proposed in 1902. Includes observations, thoughts, hypotheses, and predictions.
http://www.people.virginia.edu/~rjh9u/garrod1.html